Aschenbrenner, Jürgen C. and Korber, Nikolaus (2004) Synthesis and crystal structure of the hydrogen polyphosphide bis(tetraphenylphosphonium) hydrogenheptaphosphide-ammonia(1/3) (PPh4)(2)HP7 center dot 3NH(3). ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 630 (1). pp. 31-32. ISSN 0044-2313, 1521-3749
Full text not available from this repository. (Request a copy)Abstract
(PPh4)(2)HP7 . 3NH(3) was prepared by the reaction of K3P7 with a proton-charged ion exchange resin in the presence of (PPh4)Br in liquid ammonia.. and characterized by low temperature X-ray structure analysis. The thermally very unstable compound contains the hydrogenheptaphosphide anion HP2-, the nortricy-clane-like cage of which is slightly distorted by the attachment of the hydrogen atom.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOSPHORUS; CHEMISTRY; HEPTAPHOSPHIDE; SALT; phosphorus; hydrogen polyphospide; heptaphosphide; crystal structure |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 27 Jul 2021 09:06 |
| Last Modified: | 27 Jul 2021 09:06 |
| URI: | https://pred.uni-regensburg.de/id/eprint/38289 |
Actions (login required)
 |
View Item |
