Kunkely, Horst and Vogler, Arnd (2000) Optical outer-sphere charge transfer in aqueous ion pairs with sulfidic anions as donors. INORGANICA CHIMICA ACTA, 310 (2). pp. 279-281. ISSN 0020-1693, 1873-3255
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Various sulfidic anions and the oxidizing cations [Ru(NH3)(6)](3+) and N,N'-dimethyl-4,4'-bipyridinium(2 +) (paraquat(2+)) form ion pairs in aqueous solutions which display outer-sphere charge-transfer (CT) absorptions. The CT energies are used to establish a series of sulfidic anions with increasing CT donor strength: SCN- <S2O32- < SbS43- < PO3S3- < C(OEt)S-2(-) <P(OEt)(2)S-2(-) < WS42- (C) 2000 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ELECTRON-TRANSFER; PHOTOCHEMISTRY; COMPLEX; charge transfer; sulfidic anions; UV spectra |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 08 Mar 2022 14:28 |
| Last Modified: | 08 Mar 2022 14:28 |
| URI: | https://pred.uni-regensburg.de/id/eprint/41975 |
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