Kunkely, Horst and Vogler, Arnd (2000) Photoluminescence of 8-quinolinolato(trioxo) rhenium(VII). INORGANIC CHEMISTRY COMMUNICATIONS, 3 (11). pp. 645-647. ISSN 1387-7003
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The complex (ReO3)-O-VII(oxinate) (oxine = 8-quinolinol or 8-hydroxyquinoline) shows a green fluorescence at lambda (max) = 511 nm with phi = 0.012 and a very weak red phosphorescence at lambda (max) = 645 nm. Both emissions originate from the lowest-energy pi pi* intraligand state of the oxinate ligand. Owing to the d(0) electron configuration and the high oxidation state of rhenium the heavy atom effect transmitted to the pi -electron system of the oxinate ligand is very weak. (C) 2000 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | EXCITED-STATE PROPERTIES; CHARGE-TRANSFER; ROOM-TEMPERATURE; IMIDO COMPOUNDS; FLUID SOLUTION; LUMINESCENCE; COMPLEXES; TANTALUM; SPECTRA; rhenium complexes; luminescence |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 21 Mar 2022 06:50 |
| Last Modified: | 21 Mar 2022 06:50 |
| URI: | https://pred.uni-regensburg.de/id/eprint/42094 |
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