Kunkely, Horst and Vogler, Arnd (2000) Photochemistry of the 8-quinolinol adduct of methyltrioxorhenium(VII). JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 136 (3). pp. 175-177. ISSN 1010-6030
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MeReO3 forms a violet adduct with oxine (8-quinolinol or 8-hydroxyquinoline). MeReO3(oxine) shows a long-wavelength absorption at lambda(max) = 540 nm which is assigned to a. CH3- --> oxine (ligand-ligand charge transfer) transition. LLCT excitation leads to the formation of methane and ReO3(oxinate) as stable photoproducts with phi = 0.0015 at lambda(irr) = 546 nm in CH3CN. (C) 2000 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CHARGE-TRANSFER; OXIDES; PHOTOLUMINESCENCE; COMPLEXES; charge transfer; rhenium complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 23 Mar 2022 07:23 |
| Last Modified: | 23 Mar 2022 07:23 |
| URI: | https://pred.uni-regensburg.de/id/eprint/42198 |
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