Kunkely, Horst and Vogler, Arnd (2000) Photoluminescence of tris(pyrazolyl) hydridoborato thallium(I) complexes. CHEMICAL PHYSICS LETTERS, 327 (3-4). pp. 162-164. ISSN 0009-2614
Full text not available from this repository. (Request a copy)Abstract
The coordination compounds TlTp(3-R) with Tp(3-R) = hydridotris-(3-R-pyrazolyl-1-yl)-borate anion (R = tert-butyl, phenyl, 2-thienyl and p-tolyl) show a photoluminescence which originates from the metal-centered sp triplet of the Tl+ ion. In the solid state, the emission wavelength depends on the substituent R. Since the Tl+...Tl+ distance varies with R the emission energy seems to reflect the extent of metal-metal interaction in the excited state. (C) 2000 Published by Elsevier Science B.V.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PYRAZOLE-DERIVED LIGANDS; MAIN GROUP-METALS; COORDINATION CHEMISTRY; PHOTOCHEMISTRY; TL(I)-TL(I); STATE; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 23 Mar 2022 09:52 |
| Last Modified: | 23 Mar 2022 09:52 |
| URI: | https://pred.uni-regensburg.de/id/eprint/42207 |
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