Kunkely, Horst and Vogler, Arnd (2000) Photoreactivity of the triphenylphosphine adduct of methyl(trioxo)rhenium(VII) induced by ligand-to-metal charge transfer excitation. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 606 (2). pp. 207-209. ISSN 0022-328X
Full text not available from this repository. (Request a copy)Abstract
Triphenylphosphine forms an adduct with MeReO3. The yellow colour of this compound is attributed to a (PPh3-->Re-VII) ligand-to-metal charge transfer (LMCT) absorption at lambda(max) = 380 nm. LMCT excitation (lambda(irr) = 405 nm) leads to the reduction of Re(VII) to Re(V). This reaction has been previously observed as a thermal process (Herrmann et al., Organometallics 13 (1994) 4531. (C) 2000 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MAIN-GROUP ELEMENTS; TRANSITION-METALS; MULTIPLE BONDS; METHYLTRIOXORHENIUM(VII); PHOTOCHEMISTRY; OXIDES; CATALYSTS; photochemistry; charge transfer; rhenium; phosphines |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 30 Mar 2022 12:16 |
| Last Modified: | 30 Mar 2022 12:16 |
| URI: | https://pred.uni-regensburg.de/id/eprint/42311 |
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