Vogler, Arndt and Kunkely, Horst (2000) Excited state properties of organometallic compounds of rhenium in high and low oxidation states. COORDINATION CHEMISTRY REVIEWS, 200. pp. 991-1008. ISSN 0010-8545
Full text not available from this repository.Abstract
Organometallic compounds of rhenium occur in high and low oxidation states. These complexes are characterized by a variety of excited states including ligand held (LF), ligand-to-metal charge transfer (LMCT), metal-to-ligand charge transfer (MLCT), ligand-to-ligand charge transfer (LLCT), metal-to-metal charge transfer (MMCT), and intraligand (IL) excited states. The nature of the lowest-energy excited state can be tuned by the choice of appropriate ligands and metal oxidation states. This diversity is illustrated by selected examples of organometallics of Re(VII) and Re(I). Our account emphasizes spectral (absorption and emission) as well as photochemical properties. (C) 2000 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MAIN-GROUP ELEMENTS; LIGAND CHARGE-TRANSFER; MIXED-VALENCE COMPOUNDS; TRANSITION-METALS; MULTIPLE BONDS; CARBON-DIOXIDE; ORGANORHENIUM(VII) OXIDES; 1,2-DIIMINETRICARBONYLRHENIUM(I)CHLORIDE COMPLEXES; SPECTROSCOPIC PROPERTIES; COORDINATION CHEMISTRY; Rhenium(VII); Rhenium(I); absorption spectra; emission spectra; photochemistry; organometallics |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Petra Gürster |
| Date Deposited: | 28 Apr 2021 10:40 |
| Last Modified: | 28 Apr 2021 10:40 |
| URI: | https://pred.uni-regensburg.de/id/eprint/42504 |
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