Kunkely, Horst and Vogler, Arnd (2000) Optical charge transfer in the ion pair paraquat(2+) [Au(CN)(2)](-). INORGANIC CHEMISTRY COMMUNICATIONS, 3 (5). pp. 205-207. ISSN 1387-7003, 1879-0259
Full text not available from this repository. (Request a copy)Abstract
In aqucous solution paraquat(2+) (N,N'-dimethyl-4,4'-bipyridinium(2+)) and [Au(CN)(2)](-) form an ion pair (K similar to 90 M-1) which shows an outer-sphere [Au(CN)(2)](-) to paraquat(2+) charge transfer (CT) abaorption at lambda(max) = 331 nm. A band analysis yields a potential of E-o similar to 3.2 V for the one-electron oxidation of [Au(CN)(2)](-). Accordingly, Au(I) is a very weak CT donor. (C) 2000 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSFER EXCITATION; METAL-COMPLEXES; PHOTOCHEMISTRY; LUMINESCENCE; SPECTRA; charge transfer; cyano complexes; gold(I) complexes; UV spectra |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 May 2022 06:53 |
| Last Modified: | 10 May 2022 06:53 |
| URI: | https://pred.uni-regensburg.de/id/eprint/42518 |
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