Kunkely, Horst and Vogler, Arnd (2000) Luminescence detection and photodimerization of 1,3-dimethyluracil coordinated to copper(I). ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 55 (5). pp. 386-388. ISSN 0932-0776
Full text not available from this repository. (Request a copy)Abstract
1,3-Dimethyluracil (DMU) forms a complex with copper(I) iodide which shows a green luminescence at lambda(max) = 505 nm. With PF6- counterions a photoactive Cu(I)DMU complex is generated which shows a long-wavelength absorption at lambda(max) = 335 nm. Light absorption by this band leads to a dimerization of DMU to its cyclobutane dimer.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOTOASSISTED VALENCE ISOMERIZATION; METAL-COMPLEXES; SKIN-CANCER; DNA; NORBORNADIENE; SUNLIGHT; D10; photochemistry; copper(I); uracil; luminescence |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 May 2022 13:42 |
| Last Modified: | 10 May 2022 13:42 |
| URI: | https://pred.uni-regensburg.de/id/eprint/42560 |
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