Kunkely, Horst and Vogler, Arnd (2000) Photochemical water reduction by molybdenum tetrachloride. TRANSITION METAL CHEMISTRY, 25 (2). pp. 237-238. ISSN 0340-4285
Full text not available from this repository. (Request a copy)Abstract
The photolysis of MoCl4(MeCN)(2) in MeCN in the presence of small amounts of H2O proceeds according to the equation (MoCl4)-Cl-IV. H2O --> (MoOCl4)-O-VI + H-2. It is suggested that a ligand field excited state of MoCl4(H2O)(n), which is initially populated by light absorption, is deactivated to a reactive metal-to-ligand (Mo-IV --> H2O) charge transfer state.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ENZYMES; OXYGEN; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 24 May 2022 07:11 |
| Last Modified: | 24 May 2022 07:11 |
| URI: | https://pred.uni-regensburg.de/id/eprint/42718 |
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