Moussa, Mehdi Elsayed and Piesch, Martin and Fleischmann, Martin and Schreiner, Andrea and Seidl, Michael and Scheer, Manfred (2018) Highly soluble Cu(I)-acetonitrile salts as building blocks for novel phosphorus-rich organometallic-inorganic compounds. DALTON TRANSACTIONS, 47 (45). pp. 16031-16035. ISSN 1477-9226, 1477-9234
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The synthesis of the air-stable and highly soluble Cu(I-acetonitrile salts [Cu(CH3CN)(3.5)][FAL] (1) ([FAL] = FAL{OC(C6F10)(C6F5)}(3)) and [Cu(CH3CN)(4)][TEF] (2) ([TEF] = Al{OC(CF3)(3)}(4)) is presented. Compound 1 reacts with the organometallic polyphosphorus complexes [Cp2Mo2(CO)(4)(eta(2)-P-2)] (A) and [(Cp*Fe(eta(5)-P-5)] (B) and salt 2 reacts with B to form one new (3) and three unprecedented (4-6) phosphorus-rich Cu(I) dimers with the general formulas [Cu-2(mu,eta(1):eta(1)-A)(2)(eta(2)-A)(2)][FAL](2) (3), [Cu-2(mu,eta(1):eta(1)-A)(2)(eta(1)-CH3CN)(4)][FAL](2) (4), [Cu-2(mu,eta(1):eta(1)-B)(2)(eta(1)-CH3CN)(4)][FAL](2) (5) and [Cu-2(mu,eta(1):eta(1)-B)(2)(eta(1)-CH3CN)(4)][TEF](2) (6).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | N-LIGAND COMPLEXES; COPPER(I) COMPLEXES; SUPRAMOLECULAR ASSEMBLIES; COORDINATION CHEMISTRY; IN-VITRO; PENTAPHOSPHAFERROCENE; SILVER(I); BEHAVIOR; MOLECULE; DESIGN; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 04 Oct 2019 06:48 |
| Last Modified: | 04 Oct 2019 06:48 |
| URI: | https://pred.uni-regensburg.de/id/eprint/13363 |
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