A simple approach for simultaneous detection of cadmium(II) and lead(II) based on glutathione coated magnetic nanoparticles as a highly selective electrochemical probe

Baghayeri, Mehdi and Amiri, Amirhassan and Maleki, Behrooz and Alizadeh, Zahra and Reiser, Oliver (2018) A simple approach for simultaneous detection of cadmium(II) and lead(II) based on glutathione coated magnetic nanoparticles as a highly selective electrochemical probe. SENSORS AND ACTUATORS B-CHEMICAL, 273. pp. 1442-1450. ISSN 0925-4005,

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Abstract

We introduce the synthesis and electrochemical application of a glutathione functionalized magnetic nano composite (GSH@Fe3O4) for the development of a simple, stable and selective sensor for heavy metal ion detection in real-life samples for the first time. The monitoring method is based on electrochemical pre-concentration/reduction of metal ions onto a GSH@Fe3O4 modified magnetic glassy carbon electrode, followed by subsequent anodic stripping. This method allows the detection of Pb2+ and Cd2+ ions with high sensitivity (calculated detection limits of 0.182 mu gL(-1) and 0.172 mu gL(-1)), low cost, and great convenience in operation and was tested for different water samples. The results infer that the GSH@Fe3O4 nanocomposite can be an alternative candidate for practical applications in electrochemical detection of metal ions.

Item Type: Article
Uncontrolled Keywords: STRIPPING VOLTAMMETRIC DETERMINATION; FE3O4 NANOPARTICLES; MODIFIED ELECTRODES; GLUCOSE-OXIDASE; FILM ELECTRODE; HEAVY-METALS; CARBON; GRAPHENE; BIOSENSOR; SENSOR; Stripping voltammetry; Cadmium(II); Lead(II); Nanocomposite; Glutathione
Subjects: 500 Science > 530 Physics
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Depositing User: Dr. Gernot Deinzer
Date Deposited: 10 Oct 2019 06:11
Last Modified: 10 Oct 2019 06:11
URI: https://pred.uni-regensburg.de/id/eprint/13544

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