Charkin, D. O. and Plokhikh, I. and Zadoya, A. and Kuznetsova, P. L. and Kazakov, S. M. and Siidra, O. (2018) CdBiO2NO3, a new layered bismuth oxide nitrate. SOLID STATE SCIENCES, 84. pp. 23-27. ISSN 1293-2558, 1873-3085
Full text not available from this repository. (Request a copy)Abstract
Step-wise reaction of CdO, Bi2O3, and Cd(NO3)(2)center dot 4H(2)O leads to formation of a novel bismuth oxide nitrate, CdBiO2NO3, which completes the family of bis-muthite-like (MBiO2NO3)-Bi-II oxide nitrates. The new compound is tetragonal, I4/mmm, a = 3.9486(1)angstrom, c = 14.2235(2)angstrom; its crystal structure resembles those of PbBiO2NO3 and CdBiO2NO3, except for, probably, different positioning of the nitrate group. The compound is stable until similar to 425 degrees C when it decomposes, in one step, into CdO and a mixture of Bi-Cd oxides. Cd-based analogs of isostructural PbLnO(2)NO(3 )(Ln - lanthanides) oxide nitrates are unlikely to exist. We discuss the similarities and differences in the structures of layered oxyhalides and oxynitrates of bismuth and rare-earths.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CRYSTAL-STRUCTURES; THERMAL-DECOMPOSITION; COMPOUND; FLUORIDE; PR; ND; SM; LN; |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 09 Dec 2019 10:05 |
| Last Modified: | 09 Dec 2019 10:06 |
| URI: | https://pred.uni-regensburg.de/id/eprint/13745 |
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