Marzo, Leyre and Pagire, Santosh K. and Reiser, Oliver and Koenig, Burkhard (2018) Visible-Light Photocatalysis: Does It Make a Difference in Organic Synthesis? ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 57 (32). pp. 10034-10072. ISSN 1433-7851, 1521-3773
Full text not available from this repository. (Request a copy)Abstract
Visible-light photocatalysis has evolved over the last decade into a widely used method in organic synthesis. Photocatalytic variants have been reported for many important transformations, such as cross-coupling reactions, -amino functionalizations, cycloadditions, ATRA reactions, or fluorinations. To help chemists select photocatalytic methods for their synthesis, we compare in this Review classical and photocatalytic procedures for selected classes of reactions and highlight their advantages and limitations. In many cases, the photocatalytic reactions proceed under milder reaction conditions, typically at room temperature, and stoichiometric reagents are replaced by simple oxidants or reductants, such as air, oxygen, or amines. Does visible-light photocatalysis make a difference in organic synthesis? The prospect of shuttling electrons back and forth to substrates and intermediates or to selectively transfer energy through a visible-light-absorbing photocatalyst holds the promise to improve current procedures in radical chemistry and to open up new avenues by accessing reactive species hitherto unknown, especially by merging photocatalysis with organo- or metal catalysis.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CROSS-COUPLING REACTIONS; PALLADIUM-CATALYZED ARYLATION; TRANSFER RADICAL-ADDITION; C-H ARYLATION; SINGLE-ELECTRON TRANSMETALATION; ANTI-MARKOVNIKOV HYDROAMINATION; ENANTIOSELECTIVE ALPHA-ALKYLATION; SELECTIVE AROMATIC CHLORINATION; TRANSFER CYCLIZATION REACTIONS; TRANSITION-METAL CATALYSIS; cross-coupling; cycloadditions; photocatalysis; radical reactions; visible light |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Petra Gürster |
| Date Deposited: | 09 Jul 2020 09:45 |
| Last Modified: | 09 Jul 2020 09:45 |
| URI: | https://pred.uni-regensburg.de/id/eprint/14058 |
Actions (login required)
 |
View Item |
