Moussa, Mehdi Elsayed and Welsch, Stefan and Lochner, Matthias and Peresypkina, Eugenia V. and Virovets, Alexander V. and Scheer, Manfred (2018) Organometallic-Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu-I Ions. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (23). pp. 2689-2694. ISSN 1434-1948, 1099-0682
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A multicomponent approach of the P-n ligand complex [Cp*Fe((5)-P-5)] (1: Cp* = (5)-C5Me5) with the ditopic organic linkers 4,4-bipyridine (2) or trans-1,2-di(pyridine-4-yl)ethene (3) in the presence of Cu-I salts of the anions [BF4](-) and [PF6](-) or the coordinating anion Br-, leads to the formation of four novel organometallic-organic hybrid polymers: the cationic 1D polymeric compounds [Cu-4{Cp*Fe(mu(3),(5:1:1)-P-5)}(2)(mu,(1:1)-C10H8N2)(4)(CH3CN)(4)](n)[BF4](4n) (4) and [Cu-4{Cp*Fe(mu(3),(5:1:1)-P-5)}(2)(mu,(1:1)-C10H8N2)(4)(CH3CN)(4)](n)[PF6](4n) (5) as well as the unique neutral threefold 2D 2D interpenetrated networks [Cu2Cl2{Cp*Fe(mu(3),(5:1:1)-P-5)}(mu,(1:1)-C12H10N2)](n) (6) and [Cu2Br2{Cp*Fe(mu(3),(5:1:1)-P-5)}(mu,(1:1)-C10H8N2)](n) (7).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COORDINATION POLYMERS; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; DIPHOSPHORUS COMPLEX; LIGAND COMPLEX; NETWORKS; 2D; DICHLOROMETHANE; SUPRAMOLECULE; ABSTRACTION; Ferrocene ligands; Hybrid polymers; Coordination modes; Copper; Ligand effects |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 13 Feb 2020 14:06 |
| Last Modified: | 13 Feb 2020 14:06 |
| URI: | https://pred.uni-regensburg.de/id/eprint/14382 |
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