Brunner, Henri and Tsuno, Takashi (2018) Trend-Analysis of Solid-State Structures: Low-Energy Conformational "Reactions' Involving Directed and Coupled Movements in Half-Sandwich Compounds [CpFe(CO){C(=O)R}PPh3]. CHEMISTRYOPEN, 7 (5). pp. 313-318. ISSN 2191-1363,
Full text not available from this repository. (Request a copy)Abstract
Trends in solid-state structures were used to identify preferred intramolecular movements in half-sandwich compounds [CpFe(CO){C(=O)R}PPh3]. Three weak interactions were analyzed: 1)the CH/ donor-acceptor interaction of phenyl rings in the PPh3 ligand, 2)the Ph-PPh3 face-on Cp stabilization, and 3)the hydrogen bond between the oxygen atom of the acyl group and an ortho-C-H bond of one of the PPh3 phenyl rings. Clockwise and counter-clockwise rotations established directed and coupled movements of the PPh3 ligand, the acyl group, and the phenyl rings within the PPh3 ligand.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CH/PI INTERACTIONS; CRYSTAL-STRUCTURES; PPH3 PROPELLER; PROTEINS; DATABASE; BINDING; donor-acceptor interactions; half-sandwich iron complexes; hydrogen bonding; propellers; triphenylphosphine |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 23 Mar 2020 10:49 |
| Last Modified: | 23 Mar 2020 10:49 |
| URI: | https://pred.uni-regensburg.de/id/eprint/14635 |
Actions (login required)
 |
View Item |
