Moussa, Mehdi Elsayed and Welsch, Stephan and Gregoriades, Laurence J. and Balazs, Gabor and Seidl, Michael and Scheer, Manfred (2018) The Diphosphorus Complex [Cp2Cr2(CO)(4)(eta(2)-P-2)] as a Building Block in the Coordination Chemistry of Silver. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (15). pp. 1683-1687. ISSN 1434-1948, 1099-0682
Full text not available from this repository. (Request a copy)Abstract
The reaction of the tetrahedral diphosphorus complex [Cp2Cr2(CO)(4)(eta(2)-P-2)] (Cp = C5H5) (2) with Ag[Al{OC(CF3)(3)}(4)] (AgTEF) (3) leads to the formation of the Ag-I dimer [Ag-2(eta(2)-2) (eta(1)-2)(eta(1):eta(1)-2)(2)][TEF](2) (5). This dimer can be used as a suitable precursor for the synthesis of the unprecedented 1D organometallic-organic hybrid polymer [Ag-2(eta(1)-2)(2)(mu,eta(1):eta(1)-2)(2){mu,eta(1):eta(1)-(C8H4N2)}](n)[TEF](2n) (8) upon its reaction with 1,4-dicyanobenzene (7). The driving force for this supramolecular assembly reaction is supported by DFT calculations
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | LIGAND COMPLEXES; PENTAPHOSPHAFERROCENE; METALLACYCLES; SUPRAMOLECULE; METALLACAGES; ASSEMBLIES; BEHAVIOR; DESIGN; ANIONS; 2D; Dicyanobenzene; Hybrid polymer; Diphosphorus complex; Chromium; Silver salt |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 Mar 2020 12:47 |
| Last Modified: | 10 Mar 2020 12:47 |
| URI: | https://pred.uni-regensburg.de/id/eprint/14709 |
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