Design strategies for materials showing thermally activated delayed fluorescence and beyond: Towards the fourth-generation OLED mechanism

Yersin, Hartmut and Mataranga-Popa, Larisa and Li, Shu-Wei and Czerwieniec, Rafal (2018) Design strategies for materials showing thermally activated delayed fluorescence and beyond: Towards the fourth-generation OLED mechanism. JOURNAL OF THE SOCIETY FOR INFORMATION DISPLAY, 26 (4). pp. 194-199. ISSN 1071-0922, 1938-3657

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Abstract

Design strategies for molecules showing thermally activated delayed fluorescence (TADF) are discussed, and a new emitter concept based on an almost zero-energy-gap is developed. Thermal activation is not substantial. Applied in an organic light emitting diode, all singlet and triplet excitons are harvested directly in the lowest singlet state without time-delaying TADF. This landmarking mechanism, being beyond TADF, leads to emission decay times in the sub-s range.

Item Type: Article
Uncontrolled Keywords: LIGHT-EMITTING-DIODES; CU(I) COMPLEXES; EXCITED-STATE; EMISSION; EMITTERS; SINGLET; PHOSPHORESCENCE; TEMPERATURE; CONVERSION; direct singlet harvesting; OLED mechanism beyond TADF
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Depositing User: Dr. Gernot Deinzer
Date Deposited: 10 Mar 2020 14:01
Last Modified: 10 Mar 2020 14:01
URI: https://pred.uni-regensburg.de/id/eprint/14807

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