Duesel, Simon J. S. and Koenig, Burkhard (2018) Visible-Light-Mediated Nitration of Protected Anilines. JOURNAL OF ORGANIC CHEMISTRY, 83 (5). pp. 2802-2807. ISSN 0022-3263,
Full text not available from this repository. (Request a copy)Abstract
The photocatalytic nitration of protected anilines proceeds with riboflavin tetraacetate as an organic photoredox catalyst. Sodium nitrite serves as the NO2 source in this visible-light-driven room temperature reaction. Various nitroanilines are obtained in moderate to good yields without the addition of acid or stoichiometric oxidation agents. The catalytic cycle is closed by aerial oxygen as the terminal oxidant.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COUPLED ELECTRON-TRANSFER; C-H FUNCTIONALIZATION; PHOTOREDOX CATALYSIS; METAL-FREE; AROMATIC SULFONAMIDES; OXIDATIVE NITRATION; REDOX POTENTIALS; MILD CONDITIONS; BUTYL NITRITE; PEROXYNITRITE; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 12 Mar 2020 09:36 |
| Last Modified: | 12 Mar 2020 09:36 |
| URI: | https://pred.uni-regensburg.de/id/eprint/14913 |
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