Moussa, M. Elsayed and Attenberger, B. and Peresypkina, E. V. and Scheer, M. (2018) Neutral two-dimensional organometallic-organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl. DALTON TRANSACTIONS, 47 (4). pp. 1014-1017. ISSN 1477-9226, 1477-9234
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The reaction of the P-n ligand complex [Cp* Fe(eta(5)-P-5)] (1: Cp* = eta(5)-C5Me5) with CuCl in the presence of 4,4'-bipyridine or 1,2-di(4-pyridyl) ethylene leads to the formation of three unprecedented neutral 2D organometallic-organic hybrid networks, the constitutional isomers [Cu2Cl2{Cp* Fe(mu(3), eta(5:1:1)-P-5)}(mu, eta(1:1)-C10H8N2)](n) (2 and 3) and the coordination polymer [(CuCl)(2){Cp* Fe(mu(3), eta(5:1:1)-P-5)}( mu, eta(1:1)-C12H10N2)](n) (4) with isomeric square (2 and 3) and honeycomb (4) layer topologies.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COORDINATION NETWORKS; BUILDING-BLOCKS; LIGAND COMPLEX; FRAMEWORKS; BEHAVIOR; DESIGN; 2D; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 20 Mar 2020 14:47 |
| Last Modified: | 20 Mar 2020 14:47 |
| URI: | https://pred.uni-regensburg.de/id/eprint/15175 |
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