Visible-Light-Mediated alpha-Arylation of Enol Acetates Using Aryl Diazonium Salts

Hering, Thea and Hari, Durga Prasad and Koenig, Burkhard (2012) Visible-Light-Mediated alpha-Arylation of Enol Acetates Using Aryl Diazonium Salts. JOURNAL OF ORGANIC CHEMISTRY, 77 (22). pp. 10347-10352. ISSN 0022-3263,

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Abstract

Visible light mediates efficiently the alpha-arylation of enol acetates by aryl diazonium salts under mild conditions using [Ru(bpy)(3)]-Cl-2 as a photoredox catalyst. The broad scope of the reaction toward various diazonium salts and enol acetates was explored. The application of this reaction in the concise synthesis of 2-substituted indoles was demonstrated

Item Type: Article
Uncontrolled Keywords: C-H ARYLATION; PHOTOREDOX CATALYSIS; SUBSTITUTED INDOLES; MEERWEIN ARYLATION; PSCHORR REACTION; METHYL KETONES; METAL-FREE; ETHERS; PHOTOCATALYSIS; HALIDES;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Dr. Gernot Deinzer
Date Deposited: 04 May 2020 07:09
Last Modified: 04 May 2020 07:09
URI: https://pred.uni-regensburg.de/id/eprint/17801

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