Kunkely, Horst and Vogler, Arnd (2012) Photolysis of Zeise salt in aqueous solution Photocatalysis of the hydration of olefins to alcohols. INORGANIC CHEMISTRY COMMUNICATIONS, 24. pp. 134-135. ISSN 1387-7003,
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The photolysis of aqueous Zeise salt essentially leads to the release of ethylene, but about 10% undergo a photohydration which is initiated by MLCT excitation: (PtCl3)-Cl-II(C2H4)(-) + 2H(2)O-h nu ->[Pt-II(H2O)Cl-3](-) + CH3CH2OH Since [Pt(H2O)Cl-3](-) adds again ethylene to regenerate [Pt(C2H4)Cl-3](-) the overall reaction proceeds as a photocatalysis converting C2H4 to C2H5OH. When ethylene was replaced by 1-hexene the photoaquation to 1-hexanol takes place with TON>2.30. (C) 2012 Published by Elsevier B.V.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOTOCHEMISTRY; COMPLEXES; Coordination chemistry; Zeise salt; Photocatalysis; Platinum complexes; Olefin complexes; Photochemistry |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 05 May 2020 08:28 |
| Last Modified: | 05 May 2020 08:28 |
| URI: | https://pred.uni-regensburg.de/id/eprint/17993 |
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