Kunkely, Horst and Vogler, Arnd (2012) Photolysis of aqueous [Os(NH3)(5)(N-2)](2+): Dismutation of coordinated dinitrogen. INORGANICA CHIMICA ACTA, 391. pp. 229-231. ISSN 0020-1693,
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Aqueous [Os-II(NH3)(5)(N-2)](2+) undergoes a photolysis with UV light (lambda(irr) = 254 nm). The main photoreaction proceeds according to the equation: [Os-II(NH3)(5)(N-2)](2+) + O-2 -> [Os-VI(NH3)(4)N](3+) + NO2- + NH3. The photolysis can thus be viewed as photodismutation of the coordinated N2 ligand yielding N-III (nitride) and N+III (nitrite). This reaction is coupled with an additional redox process: (Os-II + O-2 -> Os-VI + 2O(2)). (C) 2012 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOTOCHEMISTRY; COMPLEXES; Coordination chemistry; Osmium; Photochemistry; Dinitrogen |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 07 May 2020 05:26 |
| Last Modified: | 07 May 2020 05:26 |
| URI: | https://pred.uni-regensburg.de/id/eprint/18272 |
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