Probing individual weakly-coupled pi-conjugated molecules on semiconductor surfaces

Muennich, G. and Albrecht, F. and Nacci, C. and Utz, M. and Schuh, D. and Kanisawa, K. and Foelsch, S. and Repp, J. (2012) Probing individual weakly-coupled pi-conjugated molecules on semiconductor surfaces. JOURNAL OF APPLIED PHYSICS, 112 (3): 034312. ISSN 0021-8979, 1089-7550

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Abstract

A weak perturbation of a single molecule by the supporting substrate is a key ingredient to molecular electronics. Here, we show that individual phthalocyanine molecules adsorbed on GaAs(110) and InAs(111)A surfaces represent prototypes for weakly coupled single-molecule/semiconductor hybrid systems. This is demonstrated by scanning tunneling spectroscopy and bias-dependent images that closely resemble orbital densities of the free molecule. This is in analogy to results for molecules decoupled from a metal substrate by an ultrathin insulating layer and proves a weak electronic molecule-substrate coupling. Therefore, such systems will allow single-molecule functionality to be combined with the versatility of semiconductor physics. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4742977]

Item Type: Article
Uncontrolled Keywords: SCANNING-TUNNELING-MICROSCOPY; METAL PHTHALOCYANINES; ELECTRONIC-STRUCTURE; GAAS(110) SURFACE; SI(100) SURFACE; SPECTROSCOPY; ADSORPTION; CHEMISTRY; DEVICES; VACANCY;
Subjects: 500 Science > 530 Physics
Divisions: Physics > Institute of Experimental and Applied Physics
Physics > Institute of Experimental and Applied Physics > Chair Professor Giessibl > Group Jascha Repp
Depositing User: Dr. Gernot Deinzer
Date Deposited: 08 May 2020 05:04
Last Modified: 08 May 2020 05:04
URI: https://pred.uni-regensburg.de/id/eprint/18344

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