Photoluminescence behavior of riboflavin and lumiflavin in liquid solutions and solid films

Penzkofer, Alfons (2012) Photoluminescence behavior of riboflavin and lumiflavin in liquid solutions and solid films. CHEMICAL PHYSICS, 400. pp. 142-153. ISSN 0301-0104,

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Abstract

The absorption and emission behavior of riboflavin and lumiflavin in water, tetrahydrofuran (THF), water-starch, THF-polystyrene, starch films, and polystyrene films was studied at room temperature. Absorption cross-section spectra, fluorescence quantum distributions, and fluorescence quantum yields were determined. For the starch films additionally phosphorescence and delayed fluorescence spectra as well as phosphorescence lifetimes and delayed fluorescence lifetimes were measured and their quantum yields of intersystem-crossing, intrinsic triplet-based phosphorescence quantum yields, T-1-S-0 radiative lifetimes, and S-0-T-1 absorption strengths were calculated. A method of absolute intrinsic luminescence quantum distribution and quantum yield determination for dye doped films on transparent plates with a fluorimeter is described. (C) 2012 Elsevier B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: BLUE-LIGHT PHOTORECEPTORS; SINGLET OXYGEN YIELDS; AQUEOUS-SOLUTION; CHLAMYDOMONAS-REINHARDTII; EXCITED-STATES; QUANTUM YIELD; PHOTOPHYSICAL PROPERTIES; FLAVIN DERIVATIVES; EMISSION BEHAVIOR; PH-DEPENDENCE; Riboflavin; Lumiflavin; Starch films; Polystyrene films; Fluorescence; Phosphorescence; Delayed fluorescence; Luminescence quantum yields; Luminescence lifetimes; Quantum yield of intersystem-crossing
Subjects: 500 Science > 530 Physics
Divisions: Physics > Institute of Experimental and Applied Physics > Alumni or Retired Professors > Group Günther Bayreuther
Depositing User: Dr. Gernot Deinzer
Date Deposited: 13 May 2020 12:03
Last Modified: 13 May 2020 12:03
URI: https://pred.uni-regensburg.de/id/eprint/18719

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