Kunkely, Horst and Vogler, Arnd (2012) Photolysis of Aqueous [Os(NH3)(5)(N-2)](2+). Photoreduction of Coordinated Dinitrogen to Hydrazine as a Model for a New Type of Artificial Photosynthesis? ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 67 (5). pp. 488-490. ISSN 0932-0776, 1865-7117
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In the absence of oxygen the photolysis of [Os(NH3)(5)(N-2)](2+) leads to the reduction of the N-2 ligand according to [Os-II(NH3)(5)(N-2)](2+) + H2O -> [Os-VI(NH3)(4)](3+) + N2H4 + OH-. The photochemical formation of hydrazine from N-2 is discussed with regard to the photochemical conversion and storage of solar energy.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | RAY CRYSTAL-STRUCTURE; PHOTOCHEMISTRY; COMPLEXES; Osmium Complexes; Dinitrogen Complexes; Photochemistry; Hydrazine; Artificial Photosynthesis |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 May 2020 05:38 |
| Last Modified: | 14 May 2020 05:38 |
| URI: | https://pred.uni-regensburg.de/id/eprint/18760 |
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