Vogler, Arnd and Kunkely, Horst (2012) Photooxidation of coordinated dinitrogen. Photolysis of the ClO2 adduct of [(NH3)(5)Os(mu-N-2)Os(NH3)(5)](5+). INORGANIC CHEMISTRY COMMUNICATIONS, 18. pp. 73-74. ISSN 1387-7003, 1879-0259
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The complex [(NH3)(5)Os-II(mu-N-2)Os-III(NH3)(5)](5+) forms an adduct with ClO2 which is photoactive. It is suggested that OSCT excitation is responsible for product formation. [(NH3)(5)Os-II(mu-N-2)Os-III(NH3)(5)](5+) + (ClO2)-O-IV -> 2[Os-II(NH3)(5)(N+IIIO)(3+)] + Cl-. This reaction seems to be a unique example of oxidative splitting of a N-2 ligand. (C) 2012 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; PHOTOCHEMISTRY; ACTIVATION; OSMIUM; Coordination chemistry; Osmium; Photochemistry; Dinitrogen |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 15 May 2020 11:43 |
| Last Modified: | 15 May 2020 11:43 |
| URI: | https://pred.uni-regensburg.de/id/eprint/18973 |
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