Metal-Free, Visible-Light-Mediated Direct C-H Arylation of Heteroarenes with Aryl Diazonium Salts

Hari, Durga Prasad and Schroll, Peter and Koenig, Burkhard (2012) Metal-Free, Visible-Light-Mediated Direct C-H Arylation of Heteroarenes with Aryl Diazonium Salts. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 134 (6). pp. 2958-2961. ISSN 0002-7863,

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Abstract

Visible light along with 1 mol % eosin Y catalyzes the direct C-H bond arylation of heteroarenes with aryl diazonium salts by a photoredox process. We have investigated the scope of the reaction for several aryl diazonium salts and heteroarenes. The general and easy procedure provides a transition-metal-free alternative for the formation of aryl-heteroaryl bonds.

Item Type: Article
Uncontrolled Keywords: PHOTOREDOX CATALYSIS; EOSIN-Y; ARENEDIAZONIUM SALTS; FURAN-DERIVATIVES; ORGANIC-SYNTHESIS; PSCHORR REACTION; BOND ARYLATION; PHOTOCATALYSIS; ORGANOCATALYSIS; CYCLOADDITIONS;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Dr. Gernot Deinzer
Date Deposited: 19 May 2020 09:24
Last Modified: 19 May 2020 09:24
URI: https://pred.uni-regensburg.de/id/eprint/19229

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