Friedrich, Ute and Neumeier, Maria and Koch, Carina and Korber, Nikolaus (2012) Synthesis of heteroatomic Zintl anions in liquid ammonia - the new highly charged [Sn4Bi4](4-) and fully ordered [Sn2Bi2](2-). CHEMICAL COMMUNICATIONS, 48 (85). pp. 10544-10546. ISSN 1359-7345,
Full text not available from this repository. (Request a copy)Abstract
The new Zintl anion [Sn4Bi4](4-), synthesized by dissolving CsSnBi in liquid ammonia, forms a monocapped nortricyclane-like cage. Its electron localization function (ELF) analysis shows evidence for 3-centre bonding. The analogous reaction with KSnBi results in a crystallographically fully ordered tetrahedral [Sn2Bi2](2-) ion.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | POST TRANSITION-METALS; MAIN-GROUP ELEMENTS; HETEROPOLYATOMIC ANIONS; ELECTRON LOCALIZATION; DELTAHEDRAL CLUSTERS; IONS; POLYANIONS; CHEMISTRY; CAGE; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 22 May 2020 09:42 |
| Last Modified: | 22 May 2020 09:42 |
| URI: | https://pred.uni-regensburg.de/id/eprint/19435 |
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