Avola, Sabine and Goettmann, Frederic and Antonietti, Markus and Kunz, Werner (2012) Organic reactivity of alcohols in superheated aqueous salt solutions: an overview. NEW JOURNAL OF CHEMISTRY, 36 (8). pp. 1568-1573. ISSN 1144-0546,
Full text not available from this repository. (Request a copy)Abstract
The low dielectric constant and high self-dissociation constant of water in a temperature range between 150 and 250 degrees C make it a very appealing solvent for synthesis. Surprisingly, while organic chemistry in water at low temperature or around its critical point has been investigated in detail, very little seems to be known about the behaviour of organic molecules under hydrothermal conditions. The present work thus aims at shading some light on this field. As a start, we decided to investigate the reactions in which alcohols can undergo in water in the above-mentioned temperature range. Knowing that very strong salt effects on organic reactions have already been observed in super critical water, the impact of salt on the outcome of our tests was also investigated in detail.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | SUPERCRITICAL WATER; HYDROTHERMAL SYNTHESIS; CHEMICAL-REACTIONS; IONIZATION; CHEMISTRY; CATALYSIS; ZEOLITES; SCIENCE; BIOMASS; SOLIDS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 25 May 2020 05:14 |
| Last Modified: | 25 May 2020 05:14 |
| URI: | https://pred.uni-regensburg.de/id/eprint/19461 |
Actions (login required)
 |
View Item |
