Stubenhofer, Markus and Lassandro, Giuliano and Balazs, Gabor and Timoshkin, Alexey Y. and Scheer, Manfred (2012) Stepwise activation of "non-innocent" Cp* substituents - a Cp* based cascade reaction. CHEMICAL COMMUNICATIONS, 48 (58). pp. 7262-7264. ISSN 1359-7345,
Full text not available from this repository. (Request a copy)Abstract
Reactions of Cp* substituted pentelidene complexes with the primary phosphine Cp*PH2 yield novel polycyclic phosphorus/arsenic and carbon containing cage compounds via cascade-like reactions. These reactions include a sequence of nucleophilic addition reactions, intramolecular hydrophosphination (partially hydroarsination) reactions, retro-Diels-Alder reactions with Cp*H elimination and subsequent [2+4]-cycloadditions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOSPHORUS TRIPLE BOND; STEREOSELECTIVE FORMATION; PHOSPHINIDENE COMPLEXES; CHEMISTRY; LIGAND; RING; REARRANGEMENT; TRANSFORMATION; ALUMINUM(I); EXPANSION; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 25 May 2020 06:13 |
| Last Modified: | 25 May 2020 06:13 |
| URI: | https://pred.uni-regensburg.de/id/eprint/19473 |
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