Enantioselective synthesis of (-)- paeonilide

Harrar, Klaus and Reiser, Oliver (2012) Enantioselective synthesis of (-)- paeonilide. CHEMICAL COMMUNICATIONS, 48 (28). pp. 3457-3459. ISSN 1359-7345,

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Abstract

The first enantioselective synthesis of (-)- paeonilide is reported. Starting from inexpensive furan-3-carboxylic acid the targeted monoterpene was obtained in 12 steps via an asymmetric cyclopropanation-lactonization cascade and a stereoselective side chain insertion at an acetal-like position.

Item Type: Article
Uncontrolled Keywords: STEREOSELECTIVE-SYNTHESIS; CARBENE INSERTION; (+/-)-PAEONILIDE; DERIVATIVES; CATALYSTS; FURANS;
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Depositing User: Dr. Gernot Deinzer
Date Deposited: 25 May 2020 07:16
Last Modified: 25 May 2020 07:16
URI: https://pred.uni-regensburg.de/id/eprint/19531

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