Eosin Y Catalyzed Visible Light Oxidative C-C and C-P bond Formation

Hari, Durga Prasad and Koenig, Burkhard (2011) Eosin Y Catalyzed Visible Light Oxidative C-C and C-P bond Formation. ORGANIC LETTERS, 13 (15). pp. 3852-3855. ISSN 1523-7060, 1523-7052

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Abstract

Eosin Y catalyzes efficiently the visible light mediated coupling of sp(3) C-H bonds adjacent to the nitrogen atom in tetrahydroisoquinoline derivatives in the absence of an external oxidant. Nitroalkanes, dialkyl malonates, malononitrile, and dialkyl phophonates were used as pronucleophiles in this metal-free, visible light oxidative coupling reaction.

Item Type: Article
Uncontrolled Keywords: PHOTOREDOX CATALYSIS; TERTIARY-AMINES; H BOND; ELECTROCHEMICAL OXIDATION; ORGANIC-SYNTHESIS; IMINIUM CATION; PET PROCESSES; ALDEHYDES; ORGANOCATALYSIS; PHOTOCATALYSIS;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Dr. Gernot Deinzer
Date Deposited: 03 Jun 2020 05:45
Last Modified: 03 Jun 2020 05:45
URI: https://pred.uni-regensburg.de/id/eprint/20406

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