Prokhorov, Anton M. and Kozhevnikov, Valery N. and Kopchuk, Dmitry S. and Bernard, Helene and Le Bris, Nathalie and Tripier, Raphael and Handel, Henri and Koenig, Burkhard and Kozhevnikov, Dmitry N. (2011) 1,2,4-Triazine method of bipyridine ligand synthesis for the preparation of new luminescent Eu(III) complexes. TETRAHEDRON, 67 (3). pp. 597-607. ISSN 0040-4020,
Full text not available from this repository. (Request a copy)Abstract
The 'triazine' methodology for the synthesis of functionalized bipyridine ligands proved to be a convenient method for the preparation of luminescent Eu(III) complexes. The approach allows flexible construction of chromophore and coordination sphere with control of photophysical properties. Europium (III) complexes [Eu1]-[Eu5] prepared in this way exhibit intense long-life metal-centered luminescence in aqueous media. The aromatic substituent in the position 5 of bipyridine has a significant influence on luminescence parameters and is used to introduce functionality for bioconjugation. The complexes [Eu4] and [Eu5] bearing primary amine groups are ready-to-go luminescent 'tags' for peptide labeling. (C) 2010 Elsevier Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | SIMPLE LEGO SYSTEM; DIELS-ALDER; CYCLOADDITION PATHWAY; CONTRAST AGENTS; EUROPIUM; TERBIUM; 2,2'-BIPYRIDINE; PLATINUM(II); PYRIDINES; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 29 Jun 2020 05:52 |
| Last Modified: | 29 Jun 2020 05:52 |
| URI: | https://pred.uni-regensburg.de/id/eprint/21387 |
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