Gaertner, Stefanie and Korber, Nikolaus (2011) Polyanions of Group 14 and Group 15 Elements in Alkali and Alkaline Earth Metal Solid State Compounds and Solvate Structures. In: UNSPECIFIED Structure and Bonding,, 140 . SPRINGER-VERLAG BERLIN, BERLIN, pp. 25-57. ISBN 978-3-642-21180-5
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The chapter discusses the formation of discrete polyanions of group 14 and group 15 elements in solid state structures of alkali and alkaline earth metal compounds depending on the degree of reduction and the cation radii. Applying this concept reveals areas of stability of polyan ions of different nature. The mapping of the compounds in one diagram presents a comprehensive overview for the regions of existence of the polyanions in the discussed materials. Additionally, solvate structures are summarized, which provide a promising possibility to adjoin new polyanionic arrangements.
| Item Type: | Book Section |
|---|---|
| Uncontrolled Keywords: | ALKALIMETALLE ZU HALBMETALLEN; LOW-TEMPERATURE MODIFICATION; CRYSTALLINE COMPOUNDS <NA4.7EN>SN9; ELECTRON LOCALIZATION FUNCTION; STABLE HOMOPOLYATOMIC ANIONS; ZINTL ANIONS; VIBRATIONAL-SPECTRA; RAMAN-SPECTRUM; CHEMICAL-BOND; DAS VERHALTEN; Cation radii; Group 14; Group 15; Homoatomic polyanions; Solid state; Solution; Zintl |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 22 Jul 2020 10:12 |
| Last Modified: | 22 Jul 2020 10:12 |
| URI: | https://pred.uni-regensburg.de/id/eprint/21432 |
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