A novel approach for the separation of neutral analytes by means of electrochemically assisted injection coupled to capillary electrophoresis-mass spectrometry

Scholz, Rebekka and Matysik, Frank-Michael (2011) A novel approach for the separation of neutral analytes by means of electrochemically assisted injection coupled to capillary electrophoresis-mass spectrometry. ANALYST, 136 (8). pp. 1562-1565. ISSN 0003-2654, 1364-5528

Full text not available from this repository. (Request a copy)

Abstract

A novel concept for capillary electrophoresis-mass spectrometry (CE-MS) studies of neutral analytes is presented. The experimental approach is based on the implementation of electrochemically assisted injection (EAI) which enables the generation of charged species from neutral analytes. In this way electrophoretic separations can be performed without the use of surfactants leading to an excellent compatibility with ESI-MS. Various ferrocene species have been used as model compounds to demonstrate the potential of the EAI-CE-MS technique.

Item Type: Article
Uncontrolled Keywords: CHEMISTRY;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Analytische Chemie, Chemo- und Biosensorik > Instrumentelle Analytik (Prof. Frank-Michael Matysik)
Depositing User: Dr. Gernot Deinzer
Date Deposited: 29 Jun 2020 06:51
Last Modified: 29 Jun 2020 06:51
URI: https://pred.uni-regensburg.de/id/eprint/21462

Actions (login required)

View Item View Item