Selective picomolar detection of mercury(II) using optical sensors

Diez-Gil, Cesar and Martinez, Rosario and Ratera, Imma and Hirsh, Thomas and Espinosa, Arturo and Tarraga, Alberto and Molina, Pedro and Wolfbeis, Otto S. and Veciana, Jaume (2011) Selective picomolar detection of mercury(II) using optical sensors. CHEMICAL COMMUNICATIONS, 47 (6). pp. 1842-1844. ISSN 1359-7345,

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Abstract

The rational design of a mercury(II) ligand consisting in a 1-(4 '-oxyphenyl)-4(1 '-pyrenyl)-2,3-diaza-1,3-butadiene receptor unit, optimizes the sensitivity and reliability of a SPR sensor by the formation of a well packed SAM over the gold surface. SPR analysis allows detecting mercury(II) concentrations in aqueous systems in the picomolar range, meliorating on three orders of magnitude the EU mercury(II) detection limit in drinkable water.

Item Type: Article
Uncontrolled Keywords: SURFACE-PLASMON RESONANCE; SELF-ASSEMBLED MONOLAYERS; IMPEDANCE SPECTROSCOPY; BINDING; IONS; HG2+; NANOPARTICLES; CONTAMINATION; VOLTAMMETRY; REMEDIATION;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Analytische Chemie, Chemo- und Biosensorik > Chemo- und Biosensorik (Prof. Antje J. Bäumner, formerly Prof. Wolfbeis)
Depositing User: Dr. Gernot Deinzer
Date Deposited: 29 Jun 2020 12:53
Last Modified: 29 Jun 2020 12:53
URI: https://pred.uni-regensburg.de/id/eprint/21508

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