Improvement of (bipy)Pt(XR)(2) (X = O, S) type photosensitizers by covalent dye attachment

Pevny, Florian and Zabel, Manfred and Winter, Rainer F. and Rausch, Andreas F. and Yersin, Hartmut and Tuczek, Felix and Zalis, Stanislav (2011) Improvement of (bipy)Pt(XR)(2) (X = O, S) type photosensitizers by covalent dye attachment. CHEMICAL COMMUNICATIONS, 47 (22). pp. 6302-6304. ISSN 1359-7345,

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Abstract

Irradiation into the dye-based absorption band of complexes ((t)Bu(2)bipy)Pt(SR)(2) and ((t)Bu(2)bipy)Pt(OR)(2) where R denotes a coumarine-based thiolate and alkoxolate substituent populates the same excited triplet state as is obtained by excitation into the much weaker (RX)(2)Pt ->(t)Bu(2)bipy (X = O, S) charge-transfer band. This paves the way toward more efficient photosensitizers.

Item Type: Article
Uncontrolled Keywords: DIIMINE DITHIOLATE COMPLEXES; EXCITED-STATE; RESONANCE RAMAN; THIOLATE LIGANDS; PLATINUM(II); CHROMOPHORES; DYNAMICS; CRYSTAL;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Depositing User: Dr. Gernot Deinzer
Date Deposited: 29 Jun 2020 13:17
Last Modified: 29 Jun 2020 13:17
URI: https://pred.uni-regensburg.de/id/eprint/21510

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