Single-molecule chemistry and physics explored by low-temperature scanning probe microscopy

Swart, Ingmar and Gross, Leo and Liljeroth, Peter (2011) Single-molecule chemistry and physics explored by low-temperature scanning probe microscopy. CHEMICAL COMMUNICATIONS, 47 (32). pp. 9011-9023. ISSN 1359-7345, 1364-548X

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Abstract

It is well known that scanning probe techniques such as scanning tunnelling microscopy (STM) and atomic force microscopy (AFM) routinely offer atomic scale information on the geometric and the electronic structure of solids. Recent developments in STM and especially in non-contact AFM have allowed imaging and spectroscopy of individual molecules on surfaces with unprecedented spatial resolution, which makes it possible to study chemistry and physics at the single molecule level. In this feature article, we first review the physical concepts underlying image contrast in STM and AFM. We then focus on the key experimental considerations and use selected examples to demonstrate the capabilities of modern day low-temperature scanning probe microscopy in providing chemical insight at the single molecule level.

Item Type: Article
Uncontrolled Keywords: ATOMIC-FORCE MICROSCOPY; TUNNELING MICROSCOPE; CHARGE-STATE; VIBRATIONAL SPECTROSCOPY; CHEMICAL-STRUCTURE; FREQUENCY-SHIFTS; BOND FORMATION; RESOLUTION; SURFACE; MANIPULATION;
Subjects: 500 Science > 530 Physics
Divisions: Physics > Institute of Experimental and Applied Physics
Depositing User: Dr. Gernot Deinzer
Date Deposited: 29 Jun 2020 09:03
Last Modified: 29 Jun 2020 09:03
URI: https://pred.uni-regensburg.de/id/eprint/21512

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