Macabeo, Allan Patrick G. and Kreuzer, Andreas and Reiser, Oliver (2011) Stereoselective routes to aryl substituted gamma-butyrolactones and their application towards the synthesis of highly oxidised furanocembranoids. ORGANIC & BIOMOLECULAR CHEMISTRY, 9 (9). pp. 3146-3150. ISSN 1477-0520, 1477-0539
Full text not available from this repository. (Request a copy)Abstract
Titanium chelate addition of aryl nucleophiles to cyclopropyl aldehyde 6 followed by a tin-catalyzed one-pot retro-aldol, acetalisation and lactonisation sequence afforded cis and trans gamma-aryllactone acetals. A gamma-furyllactone derived by this approach was further transformed in two steps to model compounds for the oxidised northeastern sectors of selected Pseudopterogorgia diterpenoids.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS; ORGANOTITANIUM REAGENTS; NUCLEOPHILIC-ADDITION; CARBONYL-COMPOUNDS; FACILE SYNTHESIS; PARACONIC ACIDS; SINGLET OXYGEN; BIELSCHOWSKYSIN; ORGANOBORANES; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 01 Jul 2020 09:52 |
| Last Modified: | 01 Jul 2020 09:52 |
| URI: | https://pred.uni-regensburg.de/id/eprint/21645 |
Actions (login required)
 |
View Item |
