Chemoselective Crossed Acyloin Condensations: Catalyst and Substrate Control

Rose, Christopher A. and Gundala, Sivaji and Connon, Stephen J. and Zeitler, Kirsten (2011) Chemoselective Crossed Acyloin Condensations: Catalyst and Substrate Control. SYNTHESIS-STUTTGART (2). pp. 190-198. ISSN 0039-7881, 1437-210X

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Abstract

The interplay between catalyst and substrate control in crossed acyloin condensation reactions has been studied. It was found that a pentafluorophenyl-substituted triazolium ion derived catalyst was capable of catalyzing highly chemoselective processes between a range of aliphatic and aromatic aldehydes utilized in a 1:1 ratio.

Item Type: Article
Uncontrolled Keywords: ASYMMETRIC BENZOIN CONDENSATION; BICYCLIC THIAZOLIUM SALTS; N-HETEROCYCLIC CARBENES; CARBON BOND FORMATIONS; ALPHA-HYDROXY KETONES; ANION EQUIVALENTS; TRIAZOLIUM SALTS; ENANTIOSELECTIVE SYNTHESIS; NUCLEOPHILIC ACYLATION; LANTHANUM TRICYANIDE; organic synthesis; carbenes; heterocycles; catalysis; umpolung reactions
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Kirsten Zeitler
Depositing User: Dr. Gernot Deinzer
Date Deposited: 02 Jul 2020 12:18
Last Modified: 02 Jul 2020 12:18
URI: https://pred.uni-regensburg.de/id/eprint/21696

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