Dreher, Cornelia and Zabel, Manfred and Bodensteiner, Michael and Scheer, Manfred (2010) [(CO)(4)W(PH3)(2)] as a Source of Semi-interstitial Phosphorus Ligands in Cobalt Carbonyl Clusters. ORGANOMETALLICS, 29 (21). pp. 5187-5191. ISSN 0276-7333, 1520-6041
Full text not available from this repository. (Request a copy)Abstract
The PH3-containing complex [(CO)(4)W(PH3)(2)] (1) is synthesized in good yields by the "one-pot" reaction of [(CO)(4)W(nbd)] (nbd = norbonadiene) with P(SiMe3)(3) and subsequent methanolysis of the reaction mixture. The further reaction of [(CO)(4)W(PH3)(2)] with [Co-2(CO)(8)] results in three novel cobalt clusters, [Co-8(CO)(18)(mu(6)-P)(2)(mu-CO)] (2), [Co-10(CO)(18)(mu(7)-P)(2)(mu-CO)(6)] (3), and [[Co-3(CO)(8)-{mu(4)-PW(CO)(5)}}][(mu(4)-P)Co-3(CO)(9)]] (4). All products have been comprehensively characterized including X-ray diffraction.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOSPHINE COMPLEXES; CRYSTAL-STRUCTURE; TUNGSTEN; MOLYBDENUM; CHROMIUM; METALS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 06 Jul 2020 12:59 |
| Last Modified: | 06 Jul 2020 12:59 |
| URI: | https://pred.uni-regensburg.de/id/eprint/23887 |
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