Schneider, Gerald Johannes and Vollnhals, V. and Brandt, K. and Roth, S. V. and Goeritz, D. (2010) Correlation of mass fractal dimension and cluster size of silica in styrene butadiene rubber composites. JOURNAL OF CHEMICAL PHYSICS, 133 (9): 094902. ISSN 0021-9606,
Full text not available from this repository. (Request a copy)Abstract
The morphology of the precipitated silica VN3 filled in styrene butadiene rubber was studied as a function of the volume fraction Phi by means of small-angle X-ray scattering experiments. The wide q-range of 0.008 nm(-1)< q < 1 nm(-1) probes the structures of the primary particles, the clusters, and resolves a part of the larger clusters of the silica. The diameter of the primary particles and their surface roughness are independent from the silica concentration. The size of the clusters and the corresponding aggregation number depend on Phi. This observation could be ascribed to external mechanical forces because of the mixing process and to growing cluster-cluster interactions with increasing filler fraction. In contrast the mass fractal dimension does not depend on Phi, and by that means experimentally proving that there is not necessarily a correlation between the mass fractal dimension and the cluster size. (C) 2010 American Institute of Physics. [doi:10.1063/1.3469827]
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | SMALL-ANGLE SCATTERING; X-RAY-SCATTERING; CARBON-BLACK; DYNAMIC PROPERTIES; REINFORCEMENT; MEMBRANES; MORPHOLOGY; ELASTOMERS; FILLER; aggregation; filled polymers; fractals; mixing; nanoparticles; rubber; silicon compounds; surface roughness; X-ray scattering |
| Subjects: | 500 Science > 530 Physics |
| Divisions: | Physics > Institute of Experimental and Applied Physics > Alumni or Retired Professors > Group Dietmar Göritz |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 13 Jul 2020 08:51 |
| Last Modified: | 13 Jul 2020 08:51 |
| URI: | https://pred.uni-regensburg.de/id/eprint/24186 |
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