Wachter, Joachim (2010) Novel aspects in the coordination chemistry of mixed group 15/16 cage molecules. COORDINATION CHEMISTRY REVIEWS, 254 (17-18). pp. 2078-2085. ISSN 0010-8545
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Cage molecules with mixed group 15 (E = P, As) and group 16 elements (Q = S, Se) are versatile ligands in coordination chemistry. The introduction of solid-state techniques allows one to extend the coordination flexibility of the cage molecules and to realize new coordination modes. The use of P(4)S(3) or As(4)S(3) as building blocks in copper(I) halide networks has initiated a new kind of "soft" solid-state chemistry, in which solutions of binary inorganic cage molecules are transferred into one-, two- or three-dimensional polymers. This strategy has been stimulated by the existence of competitive phosphorus, arsenic and sulfur coordination sites in the cage molecules. (c) 2010 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METAL-COMPLEXES; CRYSTAL-STRUCTURE; TETRAPHOSPHORUS TRISULFIDE; ETA(1)-P-BASAL COORDINATION; COPPER(I) CLUSTERS; SE MOLECULES; SOLID-STATE; P4X3 X; PHOSPHORUS; LIGANDS; Pnicogen; Chalcogen; Coordination polymer; Synthesis; Crystal structure |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter |
| Depositing User: | Petra Gürster |
| Date Deposited: | 17 Apr 2020 08:57 |
| Last Modified: | 17 Apr 2020 08:57 |
| URI: | https://pred.uni-regensburg.de/id/eprint/24210 |
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