Ulbrich, Kathrin and Kreitmeier, Peter and Reiser, Oliver (2010) Microwave- or Microreactor-Assisted Conversion of Furfuryl Alcohols into 4-Hydroxy-2-cyclopentenones. SYNLETT (13). pp. 2037-2040. ISSN 0936-5214,
Full text not available from this repository. (Request a copy)Abstract
The conversion of a variety of furfuryl alcohols, derived from renewable non edible resources such as bran, into 4-hydroxy-2-cyclopentenones was accomplished using microwave irradiation. In subcritical water (220 degrees C, 15.5 bar) without the need for any catalyst the reaction proceeds approximately two orders of magnitude faster with up to twice the yield compared to methods previously reported that apply conventional heating techniques. For the parent furfuryl alcohol the process could be transferred to a microreactor, allowing the synthesis of 4-hydroxy-2-cyclopentenone in a continuous flow system on multigram scale.
Item Type: | Article |
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Uncontrolled Keywords: | ENANTIOSELECTIVE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; CARBOCYCLIC NUCLEOSIDES; ORGANIC-SYNTHESIS; CHEMISTRY; FURANS; CYCLOPENTENONES; PROSTAGLANDIN; INTERMEDIATE; DERIVATIVES; green chemistry; organic synthesis in water; microwave chemistry; carbohydrates; biomass; furfuryl alcohol |
Subjects: | 500 Science > 540 Chemistry & allied sciences |
Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
Depositing User: | Dr. Gernot Deinzer |
Date Deposited: | 22 Jul 2020 05:43 |
Last Modified: | 22 Jul 2020 05:43 |
URI: | https://pred.uni-regensburg.de/id/eprint/24435 |
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