Sensitive Determination of Water Insoluble Dyes Used as Marking of Commercial Petroleum Products Using High-Performance Liquid Chromatography with Electrochemical Detection

Goncalves Trindade, Magno Aparecido and Boldrin Zanoni, Maria Valnice and Matysik, Frank-Michael (2010) Sensitive Determination of Water Insoluble Dyes Used as Marking of Commercial Petroleum Products Using High-Performance Liquid Chromatography with Electrochemical Detection. ELECTROANALYSIS, 22 (9). pp. 955-962. ISSN 1040-0397, 1521-4109

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Abstract

This paper describes an analytical method using high-performance liquid chromatographic (HPLC) separation coupled with electrochemical detection to detect three dyes, Solvent Blue 14 (SB-14), Solvent Blue 35 (SB-35) and Solvent Red 24 (SR-24). The dyes were eluted and separated using a reversed-phase column (C-8) under isocratic elution with the mobile phase containing a mixture of acetonitrile/ammonium acetate (5.0 mmol L-1) at the ratio of 75:25 (v/v). Two sample pretreatment methods were tested and successfully applied to quantify SB14, SB-35 and SR-24 dyes in gasoline samples. The proposed method was simple, fast and suitable to detect and quantify marker dyes in gasoline sample at low concentration.

Item Type: Article
Uncontrolled Keywords: DIESEL FUELS; MARKER; SOLVENT-YELLOW-124; VALIDATION; KEROSENE; OILS; Solvent dyes; Marker dyes; Petrol sample; Fuel; Electrochemical detector; Liquid chromatography; Dyes
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Analytische Chemie, Chemo- und Biosensorik > Instrumentelle Analytik (Prof. Frank-Michael Matysik)
Depositing User: Dr. Gernot Deinzer
Date Deposited: 03 Aug 2020 05:22
Last Modified: 03 Aug 2020 05:22
URI: https://pred.uni-regensburg.de/id/eprint/24761

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