Hunger, Johannes and Buchner, Richard and Kandil, Mohamed E. and May, Eric F. and Marsh, Kenneth N. and Hefter, Glenn (2010) Relative Permittivity of Dimethylsulfoxide and N,N-Dimethylformamide at Temperatures from (278 to 328) K and Pressures from (0.1 to 5) MPa. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 55 (5). pp. 2055-2065. ISSN 0021-9568,
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Relative permittivities (epsilon(r)) have been measured at two frequencies with an expanded (k = 2) uncertainty of 0.1 usimg a re-entrant radio frequency resonator in the pressure range (0.1 to 5) MPa at temperatures from (278 to 328) K for N,N-dimethyllormamide (DMF) and (293 to 328) K for dimethylsulfoxicle (DMS0). At 298.15 K and 0.1 MPti, the assessed literature averages of 38.4 +/- 1.8 and 47.3 +/- 1.8 for DMF and DMSO, respectively, are consistent with the values of 37.2 +/- 0.1 and 46.0 +/- 0.1 determined in this work. Possible sources of uncertainty are discussed. An empirical description of epsilon(r)(p,T) is given that can be used to calculate the temperature and pressure derivatives of Er. Kirkwood g factors calculated using the present data show only minimal dipole-dipole correlations for both DMF and DMSO.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | FREQUENCY REENTRANT CAVITY; STATIC DIELECTRIC-CONSTANTS; METHANE PLUS PROPANE; WATER MIXTURES; RADIOFREQUENCY RESONATOR; CARBON-TETRACHLORIDE; MICROWAVE APPARATUS; DIMETHYL-SULFOXIDE; N-METHYLFORMAMIDE; APROTIC-SOLVENTS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 03 Aug 2020 06:23 |
| Last Modified: | 03 Aug 2020 06:23 |
| URI: | https://pred.uni-regensburg.de/id/eprint/24775 |
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