Trichlorostannyl and tris(phenylacetylenide)stannyl complexes of manganese cyclopentadienylcarbonylnitrosyl: Synthesis and molecular structures

Blokhin, A. I. and Pasynskii, A. A. and Torubaev, Yu. V. and Scheer, M. (2010) Trichlorostannyl and tris(phenylacetylenide)stannyl complexes of manganese cyclopentadienylcarbonylnitrosyl: Synthesis and molecular structures. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 36 (4). pp. 284-288. ISSN 1070-3284,

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Abstract

The heating of the ionic complex [CpMn(CO)(2)(NO)]+SnCl3-(I) in methylene chloride gives a neutral complex CpMn(CO)(NO)SnCl3 (II). The latter reacts with lithium phenylacetylenide to yield a complex CpMn(CO)(NO)Sn(Ca parts per thousand CPh)(3) (III). According to the X-ray diffraction data, complexes II and III contain shortened Mn-Sn bonds (2.5178(5) and 2.5436(12) , respectively).

Item Type: Article
Uncontrolled Keywords: ;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Depositing User: Dr. Gernot Deinzer
Date Deposited: 03 Aug 2020 10:02
Last Modified: 03 Aug 2020 10:02
URI: https://pred.uni-regensburg.de/id/eprint/24954

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