Naik, Anu and Maji, Tapan and Reiser, Oliver (2010) Iron(II)-bis(isonitrile) complexes: novel catalysts in asymmetric transfer hydrogenations of aromatic and heteroaromatic ketones. CHEMICAL COMMUNICATIONS, 46 (25). pp. 4475-4477. ISSN 1359-7345,
Full text not available from this repository. (Request a copy)Abstract
Chiral iron(II)-bis(isonitrile) complexes catalyse the transfer hydrogenation of aromatic ketones with enantioselectivities up to 91% ee, most likely via hydride transfer through imine intermediates, generated by in situ reduction of the isonitrile ligands, whereas iron acts as a Lewis acid to activate the ketone.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | IRON COMPLEX; POLAR BONDS; LIGANDS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 12 Aug 2020 09:40 |
| Last Modified: | 12 Aug 2020 09:40 |
| URI: | https://pred.uni-regensburg.de/id/eprint/25388 |
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