Gaertner, Tobias and Yoshikai, Naohiko and Neumeier, Maria and Nakamura, Eiichi and Gschwind, Ruth M. (2010) Ligand exchange reactions in Cu(III) complexes: mechanistic insights by combined NMR and DFT studies. CHEMICAL COMMUNICATIONS, 46 (25). pp. 4625-4626. ISSN 1359-7345,
Full text not available from this repository. (Request a copy)Abstract
NMR studies of (13)C/(12)C isotopic patterns in Cu(III) intermediates and reaction products together with DFT calculations of possible reaction pathways indicate an intermolecular S(N)2 like substitution mechanism for ligand exchange reactions in square planar Cu(III) complexes, which is proposed to be slow compared to reductive elimination at synthetic conditions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PLANAR PLATINUM(II) COMPLEXES; COPPER(III) INTERMEDIATE; ALKYL-HALIDES; S(N)2; SUBSTITUTION; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 12 Aug 2020 09:43 |
| Last Modified: | 12 Aug 2020 09:43 |
| URI: | https://pred.uni-regensburg.de/id/eprint/25389 |
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